Sorry, we are not sure if the Simulated Hue is the same as the Philips Hue. Currently, the lights connected to WiFi only support the Philips brand. And it requires the same WiFi connection as X1 Hub for the app to be able to connect to the hub bridge within the local area network.
Another way is to be unsure if your computer supports Bluetooth functionality. If your computer supports Bluetooth functionality, you can add a Bluetooth key in the Sofabaton app and complete pairing on your computer. In this case, you can try waking up the computer directly with commands, but you may need to try those commands that can wake up the computer and then assign the commands to the buttons you need.